I've seen this interesting little brief from the New York Times in a couple places: the modest origins of spray paint cans:
Ed Seymour, the proprietor of a Sycamore, Ill., paint company, was in
search of an easy way to demonstrate his aluminum coating for painting
radiators. His wife suggested a makeshift spray gun, like those used for
deodorizers. And so, in 1949, Seymour mixed paint and aerosol in a can
with a spray head. As it turned out, compressing paint in a can made for
a nice finish.
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